| 2007 | Karpin-Galicia | Spain | | | | 3 | 10 | Coll de Perves | 2 |
| 3 | | Port de Cantó | 1 |
|
|
| 2005 | Phonak | Spain | | | | 5 | 1 | Alto de San Jerónimo | 2 |
| 10 | 10 | Alto del Ampriu | H |
| 9 | 13 | Lagos de Covadonga | H |
| 4 | 16 | Alto de los Angeles de San Rafael | 3 |
| 3 | | Puerto de Navacerrada | 2 |
|
| 2004 | Phonak | Spain | | 3 | 15 | Col des Limouches | 2 |
| 7 | | Col de l'Echarasson | 1 |
| 4 | | Col de Carri | 3 |
| 7 | 16 | l'Alpe-d'Huez | H |
|
| |
| 2003 | Domina Vacanze | Spain | | | | 2 | 11 | Alto del Castillo | 3 |
| 5 | 20 | Alto de Abantos | 1 |
|
| 2002 | Acqua e Sapone | Spain | | | |
| 2001 | ONCE | Spain | |
| |
| 2000 | ONCE | Spain | | | | 6 | 7 | Port de Querol | 2 |
| 2 | 10 | Coll de la Creueta | 1 |
| 5 | | Super Molina | 1 |
| 7 | 11 | Alto de la Rabassa (AND) | 1 |
| 9 | 14 | Lagos de Covadonga | H |
|
| 1999 | ONCE | Spain | |
|
|
| 1998 | Kelme | Spain | |
| |
| 1997 | Kelme | Spain | | | |
| 1996 | Kelme | Spain | | | |
Santos González